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research article

Coherent Structural Dynamics of a Prototypical Charge-Density-Wave-to-Metal Transition

Huber, T.
•
Mariager, S. O.
•
Ferrer, A.
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2014
Physical Review Letters

Using femtosecond time-resolved x-ray diffraction, we directly monitor the coherent lattice dynamics through an ultrafast charge-density-wave-to-metal transition in the prototypical Peierls system K0.3MoO3 over a wide range of relevant excitation fluences. While in the low fluence regime we directly follow the structural dynamics associated with the collective amplitude mode; for fluences above the melting threshold of the electronic density modulation we observe a transient recovery of the periodic lattice distortion. We can describe these structural dynamics as a motion along the coordinate of the Peierls distortion triggered by the prompt collapse of electronic order after photoexcitation. The results indicate that the dynamics of a structural symmetry-breaking transition are determined by a high-symmetry excited state potential energy surface distinct from that of the initial low-temperature state.

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Type
research article
DOI
10.1103/PhysRevLett.113.026401
Web of Science ID

WOS:000341315100012

Author(s)
Huber, T.
Mariager, S. O.
Ferrer, A.
Schaefer, H.
Johnson, J. A.
Gruebel, S.
Luebcke, A.  
Huber, L.
Kubacka, T.
Dornes, C.
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Date Issued

2014

Publisher

American Physical Society

Published in
Physical Review Letters
Volume

113

Issue

2

Article Number

026401

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSU  
Available on Infoscience
October 23, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/107906
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