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  4. Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
 
research article

Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts

Luo, Jingshan  
•
Im, Jeong-Hyeok  
•
Mayer, Matthew Thomas  
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2014
Science

Although sunlight-driven water splitting is a promising route to sustainable hydrogen fuel production, widespread implementation is hampered by the expense of the necessary photovoltaic and photoelectrochemical apparatus. Here, we describe a highly efficient and low-cost water-splitting cell combining a state-of-the-art solution-processed perovskite tandem solar cell and a bifunctional Earth-abundant catalyst. The catalyst electrode, a NiFe layered double hydroxide, exhibits high activity toward both the oxygen and hydrogen evolution reactions in alkaline electrolyte. The combination of the two yields a water-splitting photocurrent density of around 10 milliamperes per square centimeter, corresponding to a solar-to-hydrogen efficiency of 12.3%. Currently, the perovskite instability limits the cell lifetime.

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Type
research article
DOI
10.1126/science.1258307
Web of Science ID

WOS:000342164500040

Author(s)
Luo, Jingshan  
Im, Jeong-Hyeok  
Mayer, Matthew Thomas  
Schreier, Marcel  
Nazeeruddin, Mohammad Khaja  
Park, Nam-Gyu
Tilley, S. David  
Fan, Hong Jin
Graetzel, Michael  
Date Issued

2014

Publisher

American Association for the Advancement of Science

Published in
Science
Volume

345

Issue

6204

Start page

1593

End page

1596

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
October 23, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/107644
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