A New Mechanism for Twin Growth in Mg Alloys
Twinning is an important deformation mode in lightweight Mg alloys, but the mechanisms of nucleation and growth of twins and their interactions with solutes remain largely unresolved. Here, a new model for thermally-activated, stress-driven growth of twin boundaries is presented and the role of random and segregated solutes in controlling this growth is studied analytically and using direct molecular dynamics simulations. Twin growth occurs by the thermally-activated nucleation and expansion of twin dislocation loops on a pre-existing twin boundary. Fluctuations in the local concentration of random solutes lowers the energy barrier for this process and thus facilitates twin growth. Segregation of solutes to the twin boundary strongly increases the energy barrier and suppresses twin growth. In random solid solutions at experimental strain rates, the thermally-activated nucleation process is sufficiently fast at low applied stresses so that growth of the twin is controlled by solute strengthening of the nucleated twin loop as it expands across the twin boundary. Annealing of a deformed sample leads to solute segregation and very strong pinning so that further twinning can only be accomplished by nucleation of new twins, consistent with experimental observations. The new mechanism also (i) operates for detwinning and rationalizes complex twin shapes observed in experiments and (ii) suggests a process for dynamic strain aging commonly observed in Mg alloys at elevated temperatures.
A New Mechanism_Twin Growth_Mg Alloys_Luque Ghazisaeidi Curtin_epfl.pdf
Preprint
openaccess
1.53 MB
Adobe PDF
df9973502d2ec39e0cbb5c655d69c075
PPT_Luque_TwinMgAlloy_24WCMM_main.pdf
openaccess
3.61 MB
Adobe PDF
d2ab8800b234cd3dcf94e75abc6fe882