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  4. Three-Dimensional Magneto-Photoluminescence as a Probe of the Electronic Properties of Crystal-Phase Quantum Disks in GaAs Nanowires
 
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research article

Three-Dimensional Magneto-Photoluminescence as a Probe of the Electronic Properties of Crystal-Phase Quantum Disks in GaAs Nanowires

Corfdir, Pierre
•
Van Hattem, Barbara
•
Uccelli, Emanuele  
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2013
Nano Letters

Crystal-phase engineering has emerged as a novel method of bandgap engineering, made feasible by the high surface-to-volume ratio of nanowires. There remains intense debate about the exact characteristics of the band structure of the novel crystal phases, such as wurtzite GaAs, obtained by this approach. We attack this problem via a low-temperature angle-dependent magneto-photoluminescence study of wurtzite/zinc-blende quantum disks in single GaAs nanowires. The exciton diamagnetic coefficient is proportional to the electron-hole correlation length, enabling a determination of the spatial extent of the exciton wave function in the plane and along the confinement axis of the crystal-phase quantum disks. Depending on the disk nature, the diamagnetic coefficient measured in Faraday geometry ranges between 25 and 75 mu eV/T-2. For a given disk, the diamagnetic coefficient remains constant upon rotation of the magnetic field. Along with our envelope function calculation accounting for excitonic effects, we demonstrate that the electron effective mass in wurtzite GaAs quantum disks is heavy, mostly isotropic and results from mixing of the two lower-energy conduction bands with Gamma(7) and Gamma(8) symmetries. Finally, we discuss the implications of the results of the angle dependent magneto-luminescence for the likely symmetry of the exciton states. This work provides important insight in the band structure of wurtzite GaAs for future nanowire-based polytypic bandgap engineering.

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Type
research article
DOI
10.1021/nl4028186
Web of Science ID

WOS:000327111700048

Author(s)
Corfdir, Pierre
•
Van Hattem, Barbara
•
Uccelli, Emanuele  
•
Conesa-Boj, Sonia  
•
Lefebvre, Pierre
•
Fontcuberta I. Morral, Anna  
•
Phillips, Richard T.
Date Issued

2013

Publisher

Amer Chemical Soc

Published in
Nano Letters
Volume

13

Issue

11

Start page

5303

End page

5310

Subjects

Nanowires

•

wurtzite GaAs

•

magneto-optical properties

•

photoluminescence

•

envelope function calculations

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMSC  
Available on Infoscience
January 9, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/99341
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