Insertion of Zerovalent Nickel into the N–N Bond of N-Heterocyclic-Carbene-Activated N2O

Metal-mediated cleavage of the N–N bond is a rarely observed phenomenon in the chemistry of nitrous oxide (N2O). We demonstrate that, upon activation of N2O with N-heterocyclic carbenes, zerovalent nickel is able to insert into the N–N bond to give nitrosyl complexes.


Published in:
Inorganic Chemistry, 52, 11688-11690
Year:
2013
Publisher:
Washington, Amer Chemical Soc
Laboratories:


Note: The status of this file is: EPFL only


 Record created 2013-08-28, last modified 2018-09-13

n/a:
Download fulltext
PDF

Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)