[Fe]-hydrogenase and Models Containing An Iron-Acyl Ligation

[Fe]-hydrogenase is a newly characterized type of hydrogenase. This enzyme heterolytically splits hydrogen in the presence of a natural substrate. The active site of the enzyme contains a mono-iron complex with intriguing ironacyl ligation. Several groups have recently developed ironacyl complexes as synthetic models of [Fe]-hydrogenase. This Focus Review summarizes the studies of this enzyme and its model compounds, with an emphasis on our own research in this area.


Published in:
Chemistry, An Asian Journal, 8, 6, 1068-1075
Year:
2013
Publisher:
Weinheim, Wiley-V C H Verlag Gmbh
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 Record created 2013-03-09, last modified 2018-09-13

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