research article
Direct, in situ determination of pH and solute concentrations in formic acid dehydrogenation and CO2 hydrogenation in pressurised aqueous solutions using 1H and 13C NMR spectroscopy
2013
In water, spin–lattice relaxation times (T1) and calibration curves for chemical shifts have been determined for the 13C and the 1H (C) atoms in HCOOH, HCOONa, CO2, Na2CO3 and NaHCO3 by NMR spectroscopy. These data facilitate kinetic and mechanistic studies for H2 storage/delivery in the carbon dioxide–formic acid systems under H2 and CO2 pressures.
Type
research article
Web of Science ID
WOS:000316294400005
Author(s)
Date Issued
2013
Publisher
Published in
Volume
42
Start page
4353
End page
4356
Editorial or Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
March 6, 2013
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