Fine-tuning the Electronic Structure of Organic Dyes for Dye-Sensitized Solar Cells

A series of metal-free organic dyes exploiting different combinations of (hetero)cyclic linkers (benzene, thiophene, and thiazole) and bridges (4H-cyclopenta[2,1-b:3,4-b']dithiophene (CPDT) and benzodithiophene (BDT)) as the central pi-spacers were synthesized and characterized. Among them, the sensitizer containing the thiophene and CPDT showed the most broad incident photon-to-current conversion efficiency spectra, resulting in a solar energy conversion efficiency (eta) of 6.6%.


Published in:
Organic Letters, 14, 17, 4330-4333
Year:
2012
Publisher:
Washington, American Chemical Society
ISSN:
1523-7060
Laboratories:




 Record created 2013-02-27, last modified 2018-09-13


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