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research article

Defects and localization in chemically-derived graphene

Ciric, L.  
•
Sienkiewicz, A.  
•
Gaal, R.  
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2012
Physical Review B

We have performed electron spin resonance (ESR) measurements on a large assembly of graphene oxide (GO) and reduced graphene oxide (RGO) flakes. In GO samples the Curie tail is coming from 1.4 x 10(18) cm(-3) of localized spins. Although reduction of GO was expected to reestablish the pristine properties of graphene, no Pauli-like contribution was detected and only a low concentration of 1.2 x 10(16) cm(-3) spin carrying defects were measured. Our study, completed by resistivity measurements, shows that the carrier transport in RGO samples is dominated by hopping. The incomplete reduction of GO leaves behind a large number of defects, presumably the majority of which are ESR silent, causing the Anderson localization of the electronic states. Slight doping with potassium indicates the appearance of a Pauli contribution in the spin susceptibility.

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Type
research article
DOI
10.1103/PhysRevB.86.195139
Web of Science ID

WOS:000311537100001

Author(s)
Ciric, L.  
Sienkiewicz, A.  
Gaal, R.  
Jacimovic, J.  
Vaju, C.  
Magrez, A.  
Forro, L.  
Date Issued

2012

Publisher

Amer Physical Soc

Published in
Physical Review B
Volume

86

Issue

19

Article Number

195139

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPMC  
LPCM  
Available on Infoscience
February 27, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/89237
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