Evaluating the critical thickness of TiO2 layer on insulating mesoporous templates for efficient current collection in dye-sensitized solar cells
In this paper, we present a way of utilizing thin and conformal overlayer of titanium dioxide on insulating mesoporous template as a photoanode for dye-sensitized solar cells (DSC). Different thicknesses of TiO2 ranging from 1 nm to 15 nm are deposited on the surface of the template by atomic layer deposition (ALD) technique. This systematic study helps unravelling the minimum critical thickness of the TiO2 overlayer required to transport the photogenerated electrons efficiently. A merely 6 nm thick TiO2 film on a 3 μm mesoporous insulating substrate is shown to transport 8 mA/cm2 of photocurrent density along with 900 mV of open-circuit potential when using our standard donor-π-acceptor sensitizer and Co(bipyridine) redox mediator.
Record created on 2012-11-16, modified on 2016-08-09