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research article
A Pyridinol Acyl Cofactor in the Active Site of [Fe]-hydrogenase Evidenced by the Reactivity of Model Complexes
The decomposition reaction of a water-soluble complex (see scheme; 1) in H2O confirms the existence of a unique bidentate pyridinol cofactor in [Fe]-hydrogenase. This unique moiety is confirmed for the first time by the decomposition of a well-defined model complex containing a pyridinyl methyl acyl ligand.
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Type
research article
Web of Science ID
WOS:000308313100003
Authors
Publication date
2012
Publisher
Published in
Volume
18
Issue
37
Start page
11528
End page
11530
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
July 19, 2012