Direct Femtosecond Observation of Tight and Loose Ion Pairs upon Photoinduced Bimolecular Electron Transfer

We observe tight and loose ion pairs in bimolecular electron transfer with ultrafast infrared spectroscopy. For large exergonicity tight donor-acceptor pairs do not rearrange into loose complexes before the reaction proceeds, contrasting generally accepted models.


Published in:
Ultrafast Phenomena Xvi, 92, 613-615
Year:
2009
Keywords:
Laboratories:




 Record created 2012-07-09, last modified 2018-03-17


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