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research article

Absolute absorption cross sections of ligand-free colloidal germanium nanocrystals

Holman, Zachary C.
•
Kortshagen, Uwe R.
2012
Applied Physics Letters

Extinction spectra of colloidal germanium nanocrystals suspended in benzonitrile without the use of ligands were measured, and absolute absorption cross sections are reported. Comparison to cross sections calculated using the Mie solution to Maxwell's equations reveals that, as the mean nanocrystal size is reduced from 11 to 4 nm, the absorption features below 3.5 eV blueshift because of quantum confinement effects. The shifts are not, however, sufficiently large for the nanocrystal cores to produce the blue photoluminescence commonly observed from germanium nanocrystals. At energies greater than 3.5 eV the Mie and measured cross sections overlap, indicating a bulk-like band structure. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3698091]

  • Details
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Type
research article
DOI
10.1063/1.3698091
Web of Science ID

WOS:000302230800066

Author(s)
Holman, Zachary C.
•
Kortshagen, Uwe R.
Date Issued

2012

Publisher

AIP American Institute of Physics

Published in
Applied Physics Letters
Volume

100

Article Number

133108

Subjects

Silicon Nanocrystals

•

Quantum Dots

•

Sio2

•

Ge

•

Photoluminescence

•

Matrices

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
IMT  
Available on Infoscience
May 4, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/80062
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