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research article

Electroluminescence properties of organic nanostructures studied by scanning tunnelling microscopy

Kuhnke, Klaus
•
Kabakchiev, Alexander
•
Lutz, Theresa
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2012
Physica Status Solidi B-Basic Solid State Physics

The control of light emission on the scale of individual quantum systems, like molecules or quantum dots, is a field of intense current research. One way to induce light emission from these systems is the local charge injection through the tip of a scanning tunnelling microscope (STM). Studies which employ this method have to address one basic question: Does the detected luminescence provide information precisely from the molecule into which charge is injected by the STM tip apex or are the luminescence properties determined by a larger volume? In this article, we focus on the investigation of organic nanocrystals and discuss the relation between the local excitation, the intermolecular coupling and the influence of the STM as a measuring instrument. Choosing pentacene as an organic emitter, we present results, which suggest that the STM-induced luminescence cannot be attributed simply to the emission by a single molecule. We discuss how information about locality can be obtained and comment on the present experimental limitations and possible future improvements.

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Type
research article
DOI
10.1002/pssb.201100805
Web of Science ID

WOS:000302003600002

Author(s)
Kuhnke, Klaus
Kabakchiev, Alexander
Lutz, Theresa
Kern, Klaus  
Date Issued

2012

Published in
Physica Status Solidi B-Basic Solid State Physics
Volume

249

Start page

644

End page

652

Subjects

luminescence

•

pentacene

•

photon time-correlation

•

scanning tunnelling microscopy

•

Subnanometer Lateral Resolution

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Photon-Emission

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Light-Emission

•

Induced Luminescence

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Metal-Surfaces

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Optical Recombination

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Induced Fluorescence

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C60 Molecules

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Pentacene

•

Spectroscopy

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSEN  
Available on Infoscience
May 4, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/80039
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