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research article
Multi-configurational quantum chemical studies of the Tc2X8n- (X = Cl, Br; n=2, 3) anions. Crystallographic structure of octabromoditechnetate(3(-))
2012
The [Cs(2 + x)][H3O(1 -x)]Tc2Br8 center dot 4.6H(2)O (x = 0.221) salt has been synthesized and characterized by single crystal XRD. Multi-configurational quantum chemical calculations on Tc2X8n- (X = Cl, Br; n = 2, 3) have been performed and indicate the p component in the Tc-Tc bond to be stronger for n = 3.
Type
research article
Web of Science ID
WOS:000300443000004
Authors
Poineau, Frederic
•
Forster, Paul M.
•
Todorova, Tanya K.
•
Gagliardi, Laura
•
Sattelberger, Alfred P.
•
Czerwinski, Kenneth R.
Publication date
2012
Published in
Volume
41
Start page
2869
End page
2872
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
March 15, 2012
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