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research article
In situ time-resolved DXAFS study of Rh nanoparticle formation mechanism in ethylene glycol at elevated temperature
A combination of in situ time-resolved DXAFS and ICP-MS techniques reveals that the formation process of Rh nanoparticles (NPs) from rhodium trichloride trihydrate (RhCl3 center dot 3H(2)O) in ethylene glycol with polyvinylpyrrolidone (PVP) at elevated temperature is a first-order reaction, which indicates that uniform size Rh NPs appear consecutively and these Rh NPs do not aggregate with each other.
Type
research article
Web of Science ID
WOS:000300046800003
Authors
Asakura, Hiroyuki
•
Teramura, Kentaro
•
Shishido, Tetsuya
•
Tanaka, Tsunehiro
•
•
Xiao, Chaoxian
•
Yao, Siyu
•
Kou, Yuan
Publication date
2012
Published in
Volume
14
Start page
2983
End page
2990
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
March 8, 2012
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