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research article

Improving solvent-based self-healing materials through shape memory alloys

Neuser, S.  
•
Michaud, V.  
•
White, S. R.
2012
Polymer

Healing of epoxy resins can be accomplished using a combination of embedded ethyl phenylacetate (EPA) solvent loaded capsules and shape memory alloy (SMA) wires. Upon crack formation, the EPA solvent diffuses in the resin and induces swelling which tends to close the crack, while the SMA wires upon heating reduce the crack gap and foster residual epoxy cure. The kinetics of EPA diffusion in the epoxy matrix were measured so as to evaluate the swelling thickness versus time, and concentration at saturation. The largest healable crack gap was found to be 30 mu m after 24 h. EPA solvent was shown to lower the curing reaction kinetics and the glass transition temperature (T-g) of the epoxy, as well as its stiffness and strength. Healing efficiency was assessed using long-groove tapered double cantilever beam (TDCB) test samples, with embedded SMA wires across the crack plane. The healing efficiency greatly improved when the crack gap was reduced to 30 pm, from 24% for samples without SMA wires to 78% for samples with SMA wires activated according to an optimized scenario. (C) 2011 Elsevier Ltd. All rights reserved.

  • Details
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Type
research article
DOI
10.1016/j.polymer.2011.12.020
Web of Science ID

WOS:000299607400014

Author(s)
Neuser, S.  
Michaud, V.  
White, S. R.
Date Issued

2012

Published in
Polymer
Volume

53

Issue

2

Start page

370

End page

378

Subjects

Improving solvent-based self-healing materials through shape memory alloys

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LTC  
Available on Infoscience
February 22, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/78004
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