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research article
Sequential N–O and N–N Bond Cleavage of N-Heterocyclic Carbene-Activated Nitrous Oxide with a Vanadium Complex
Chemically induced bond cleavage of nitrous oxide typically proceeds by rupture of the N–O bond with concomitant O-atom transfer and liberation of dinitrogen. On a few occasions, N–N bond scission has been observed instead. We report a reaction sequence involving an N-heterocyclic carbene and a vanadium complex that results in cleavage of both the N–O bond and the N–N bond.
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JACS-2012-Tskhovrebov.pdf
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