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  4. Effect of deposition angle on the structure and properties of pulsed-DC magnetron sputtered TiAlN thin films
 
research article

Effect of deposition angle on the structure and properties of pulsed-DC magnetron sputtered TiAlN thin films

Shetty, A. R.
•
Karimi, A.
•
Cantoni, M.  
2011
Thin Solid Films

This article reports the comparison of structure and properties of titanium aluminum nitride (TiAlN) films deposited onto Si(100) substrates under normal and oblique angle depositions using pulsed-DC magnetron sputtering. The substrate temperature was set at room temperature, 400 degrees C and 650 degrees C, and the bias was kept at 0, -25, -50, and -80 V for both deposition angles. The surface and cross-section of the films were observed by scanning electron microscopy. It was found that as the deposition temperature increases, films deposited under normal incidence exhibit distinct faceted crystallites, whereas oblique angle deposited (OAD) films develop a kind of "tiles of a roof" or "stepwise structure", with no facetted crystallites. The OAD films showed an inclined columnar structure, with columns tilting in the direction of the incident flux. As the substrate temperature was increased, the tilting of columns nearly approached the substrate normal. Both hardness and Young's modulus decreases when the flux angle was changed from alpha = 0 degrees to 45 degrees as measured by nanoindentation. This was attributed to the voids formed due to the shadowing effect. The crystallographic properties of these coatings were studied by theta-2 theta scan and pole figure X-ray diffraction. Films deposited at = 0 showed a mixed (111) and (200) out-of-plane orientation with random in-plane alignment. On the other hand, films deposited at alpha = 45 degrees revealed an inclined texture with (111) orientation moving towards the incident flux direction and the (200) orientation approaching the substrate normal, showing substantial in-plane alignment. (C) 2011 Elsevier B.V. All rights reserved.

  • Details
  • Metrics
Type
research article
DOI
10.1016/j.tsf.2011.02.090
Web of Science ID

WOS:000290187100024

Author(s)
Shetty, A. R.
Karimi, A.
Cantoni, M.  
Date Issued

2011

Published in
Thin Solid Films
Volume

519

Start page

4262

End page

4270

Subjects

Titanium aluminum nitride

•

Magnetron sputtering

•

Oblique angle deposition

•

Shadowing effect

•

Pole figures

•

X-ray diffraction

•

Nanoindentation

•

Aluminum Nitride Coatings

•

X-Ray-Diffraction

•

High-Speed Steel

•

Substrate Bias

•

Mechanical-Properties

•

Titanium Aluminum

•

Residual-Stress

•

Ion-Bombardment

•

Pvd Process

•

Iron Films

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SB  
Available on Infoscience
December 16, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/74141
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