Room-temperature combinatorial screening of cyclometallated iridium(III) complexes for a step towards molecular control of colour purity
Baranoff, Etienne; Jung, Il; Scopelliti, Rosario; Solari, Euro; Graetzel, Michael; Nazeeruddin, Md Khaja
2011

Abstract

A library of emission spectra of 90 bis-cyclometallated iridium complexes has been obtained using a simple combinatorial approach performed at room temperature. Trends in emission maxima are rationalized using Hammett parameters and invoking inter ligand energy transfer (ILET) processes. The screening approach allowed us to observe trends in the broadness of emission spectra opening the way for a rational approach to the engineering of the emission colour purity at a molecular level. Finally limitations to the screening strategy are discussed using a case study that involves two different monodentate ligands.

Details

Title Room-temperature combinatorial screening of cyclometallated iridium(III) complexes for a step towards molecular control of colour purity
Author(s) Baranoff, Etienne ; Jung, Il ; Scopelliti, Rosario ; Solari, Euro ; Graetzel, Michael ; Nazeeruddin, Md Khaja
Published in Dalton Transactions
Volume 40
Pages 6860-6867
Date 2011
Publisher Royal Society of Chemistry
ISSN 1477-9226
Keywords
DOI https://doi.org/10.1039/c0dt01697g
Other identifier(s) View record in Web of Science
Laboratories LPI
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LPI - Laboratory of Photonics and Interfaces
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2011-12-16

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