Cross coupling of non-activated alkyl halides with alkynyl Grignard reagents catalyzed by a well-defined Ni pincer complex

The nickel pincer complex 1 catalyzes the cross-coupling of the title compounds with remarkable substrate scope and functional group tolerance. A nickel/alkynyl species was isolated and shown to be catalytically competent. THF=tetrahydrofuran, O-TMEDA=bis[2-(N,N-dimethylaminoethyl)] ether.


Published in:
Angewandte Chemie International Edition, 50, 49, 11777–11781
Year:
2011
Keywords:
Laboratories:




 Record created 2011-09-24, last modified 2018-03-17


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