Homo-Brook route to benzazocenols and congeners via allylsilane-derived aziridines
Ducray, Richard; Cramer, Nicolai; Ciufolini, Marco A.
2001

Abstract

We describe a concise entry to benzazocenols intermediates, e.g. I, for mitomycinoids via a homo-Brook rearrangement-ring opening sequence of a silylated aziridine, e.g. II. The latter is obtained by intramol. 1,3-dipolar cycloaddn. of an azide with an allylsilane, followed by irradn. of the resulting triazoline.

Details

Title Homo-Brook route to benzazocenols and congeners via allylsilane-derived aziridines
Author(s) Ducray, Richard ; Cramer, Nicolai ; Ciufolini, Marco A.
Published in Tetrahedron Letters
Volume 42
Pages 9175-9178
Date 2001
Publisher Elsevier Science Ltd.
ISSN 0040-4039
Keywords
Note CAPLUS AN 2001:905526(Journal)
DOI https://doi.org/10.1016/s0040-4039(01)02018-4
Laboratories LCSA
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCSA - Laboratory of Asymmetric Catalysis and Synthesis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2011-08-17