Enantioselective synthesis of indanols from tert-cyclobutanols using a rhodium-catalyzed C-C/C-H activation sequence
2009
Abstract
Tert.-Cyclobutanols were activated through an enantioselective rhodium(I)-catalyzed insertion into the C-C bond leading to arylrhodium species. These intermediates are converted by a C-H activation mechanism to arylrhodium species that are converted to indanol derivs. in stereoselective manner.
Details
Title
Enantioselective synthesis of indanols from tert-cyclobutanols using a rhodium-catalyzed C-C/C-H activation sequence
Author(s)
Seiser, Tobias ; Roth, Olivia A. ; Cramer, Nicolai
Published in
Angewandte Chemie, International Edition
Volume
48
Pages
6320-6323
Date
2009
Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
ISSN
1433-7851
Note
CAPLUS AN 2009:998277(Journal)
Laboratories
LCSA
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCSA - Laboratory of Asymmetric Catalysis and Synthesis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2011-08-17