Enantioselective synthesis of indanols from tert-cyclobutanols using a rhodium-catalyzed C-C/C-H activation sequence
Tert.-Cyclobutanols were activated through an enantioselective rhodium(I)-catalyzed insertion into the C-C bond leading to arylrhodium species. These intermediates are converted by a C-H activation mechanism to arylrhodium species that are converted to indanol derivs. in stereoselective manner.
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Seiser, T., Roth, O. A., & Cramer, N. (2009). Enantioselective synthesis of indanols from tert-cyclobutanols using a rhodium-catalyzed C-C/C-H activation sequence. Angewandte Chemie International Edition, 48, 6320–6323. https://doi.org/10.1002/anie.200903189
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2009
48
6320
6323
CAPLUS AN 2009:998277(Journal)
REVIEWED
OTHER