Palladium-catalyzed arylative ring-opening reactions of norbornenols: entry to highly substituted cyclohexenes, quinolines, and tetrahydroquinolines
Palladium-catalyzed stereoselective arylative ring-opening reaction of norbornenol derivs. was studied. In presence of aryl bromides, corresponding cyclohexene derivs. were obtained in good yields. Meanwhile, reaction with bromoanilines yielded quinolines and tetrahydroquinolines. The asym. version of this reaction was explored by using chiral ligand.
Keywords: substituted cyclohexene stereoselective prepn ; quinoline stereoselective prepn ; norbornenol aryl bromide arylative ring opening palladium ; bromoanilne norbornenol arylative ring opening palladium
CAPLUS AN 2010:758486(Journal)
Record created on 2011-08-17, modified on 2016-08-09