Palladium-catalyzed arylative ring-opening reactions of norbornenols: entry to highly substituted cyclohexenes, quinolines, and tetrahydroquinolines

Palladium-catalyzed stereoselective arylative ring-opening reaction of norbornenol derivs. was studied. In presence of aryl bromides, corresponding cyclohexene derivs. were obtained in good yields. Meanwhile, reaction with bromoanilines yielded quinolines and tetrahydroquinolines. The asym. version of this reaction was explored by using chiral ligand.


Published in:
Angewandte Chemie, International Edition, 49, 4455-4458, S4455/1-S4455/52
Year:
2010
Publisher:
Wiley-VCH Verlag GmbH & Co. KGaA
ISSN:
1433-7851
Keywords:
Note:
CAPLUS AN 2010:758486(Journal)
Laboratories:




 Record created 2011-08-17, last modified 2018-03-17


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)