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research article
Highly selective rhodium catalyzed domino C-H activation/cyclizations
2011
The direct functionalization of carbon-hydrogen bonds is an emerging tool to establish more sustainable and efficient synthetic methods. We present its implementation in a cascade reaction that provides a rapid assembly of functionalized indanylamines from simple and readily available starting materials. Careful choice of the ancillary ligand - an electron-rich bidentate phosphine ligand - enables highly diastereoselective rhodium(I)-catalyzed intramol. allylations of unsubstituted ketimines induced by a directed C-H bond activation and allene carbo-metalation sequence.
Type
research article
Web of Science ID
WOS:000290699400018
Authors
Publication date
2011
Publisher
Published in
Volume
65
Start page
271
End page
273
Note
CAPLUS AN 2011:677119(Journal)
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
August 17, 2011
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