Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Steady-state modelling of biogeochemical processes in columns with aquifer material: 2. Dynamics of iron-sulfur interactions
 
research article

Steady-state modelling of biogeochemical processes in columns with aquifer material: 2. Dynamics of iron-sulfur interactions

Furrer, G.
•
von Gunten, U.  
2000
Chemical Geology

Serial data from column experiments were used to develop a dynamic model to describe the evolution of concentration profiles of redox-sensitive chemical components such as iron(II), sulfate/sulfide, FeOOH(s), and FeS(s). The experimental results were gained from a study with a laboratory column filled with aquifer sand and operated in a water-saturated state. "Reduction of sulfate'', "reduction of FeOOH(s)'', ''formation of FeS(s)'' and ''precipitation of FeS(s)'' were identified as slow nonequilibrium reactions. The rate coefficients of these processes were determined by using an extended version of the program STEADYQL in combination with the parameter optimisation program SUFI. Based on this kinetic information it is possible to carry out prognostic modelling of the propagation of a sulfide plume in an anaerobic aquifer if the main characteristics of thr solids' surfaces are known.

  • Details
  • Metrics
Type
research article
DOI
10.1016/S0009-2541(99)00228-4
Web of Science ID

WOS:000087135500002

Author(s)
Furrer, G.
von Gunten, U.  
Date Issued

2000

Published in
Chemical Geology
Volume

167

Start page

271

End page

284

Subjects

redox

•

aquifer

•

groundwater

•

sulfur

•

iron

•

modelling

•

Pollution Plume Vejen

•

Stability-Constants

•

Hydrogen-Sulfide

•

Pyrite Formation

•

Redox Zones

•

Kinetics

•

Mechanism

•

Waters

•

Speciation

•

Porewaters

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LTQE  
Available on Infoscience
July 1, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/69272
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés