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research article

Steric asymmetry in state-resolved NO-Ar collisions

de Lange, M. J. L.
•
Drabbels, Marcel  
•
Griffiths, P. T.
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1999
Chemical Physics Letters

New experimental results are reported on state-dependent steric effects in NO-Ar inelastic scattering. The NO molecules are selected in the J = 1/2(-) l-doublet state of the electronic ground state and oriented relative to the incident Ar atoms. The steric asymmetry, S = (sigma(NO) - sigma(ON))/(sigma(NO) + sigma(ON)), has been measured as a function of the final rotational state J'. In a previous study, quantum-mechanical scattering calculations were found to predict strong oscillations in S, but experimental evidence for this behavior was not conclusive. The results of experiments presented here provide clear evidence of the qualitative correctness of the theoretical calculations.

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Type
research article
DOI
10.1016/S0009-2614(99)01065-9
Web of Science ID

WOS:000083977700015

Author(s)
de Lange, M. J. L.
Drabbels, Marcel  
Griffiths, P. T.
Bulthuis, J.
Stolte, S.
Snijders, J. G.
Date Issued

1999

Publisher

Elsevier

Published in
Chemical Physics Letters
Volume

313

Issue

3-4

Start page

491

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCPM  
Available on Infoscience
May 10, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/67196
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