000164171 001__ 164171
000164171 005__ 20190607203322.0
000164171 02470 $$2ISI$$a000286688700005
000164171 0247_ $$2doi$$a10.1021/ic102041q
000164171 037__ $$aARTICLE
000164171 245__ $$aEnhanced rate of arene hydrogenation with imidazolium functionalized bipyridine stabilized rhodium nanoparticle catalysts
000164171 269__ $$a2011
000164171 260__ $$c2011
000164171 336__ $$aJournal Articles
000164171 520__ $$aThe imidazolium functionalized bipyridine compounds, {4,4'-bis-[7-(2,3-dimethylimidazolium)heptyl]-2,2'-bipyridine}(2+) ([BIHB](2+)) and {4,4'-bis[(1,2-dimethylimidazolium)methyl]-2,2'-bipyridine}(2+) ([BIMB](2+)), were prepared and used as Rh nanoparticle stabilizers. The dispersed Rh nanoparticles were used as catalysts in the biphasic hydrogenation of various arene substrates. The catalytic activity was strongly influenced by the stabilizer employed and followed the trend [BIHB](2+) > bipy > [BIMB](2+). The steric and electronic characteristics of the imidazolium functionalized bipyridine ligands were assessed via the synthesis of rhenium carbonyl complexes, which facilitated the rationalization of the catalytic properties of the nanoparticles.
000164171 6531_ $$aNonaqueous Ionic Liquids
000164171 6531_ $$aPalladium Nanoparticles
000164171 6531_ $$aSelective Hydrogenation
000164171 6531_ $$aBiphasic Hydrogenation
000164171 6531_ $$aMetal Nanoparticles
000164171 6531_ $$aNanocatalysts
000164171 6531_ $$aLigands
000164171 6531_ $$aNanoclusters
000164171 6531_ $$aParticles
000164171 6531_ $$aPrecursor
000164171 700__ $$0242062$$g179141$$aDykeman, R. R.
000164171 700__ $$0242070$$g181610$$aYan, N.
000164171 700__ $$g148592$$aScopelliti, R.$$0240189
000164171 700__ $$aDyson, P. J.$$0240015$$g149418
000164171 773__ $$j50$$tInorganic Chemistry$$q717-719
000164171 909C0 $$xU9$$0252010$$pLCOM
000164171 909CO $$pSB$$particle$$ooai:infoscience.tind.io:164171
000164171 917Z8 $$x179141
000164171 937__ $$aEPFL-ARTICLE-164171
000164171 973__ $$rNON-REVIEWED$$sPUBLISHED$$aEPFL
000164171 980__ $$aARTICLE