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  4. The heterogeneous reaction of NO3 with NaCl and KBr: a nonphotolytic source of halogen atoms
 
research article

The heterogeneous reaction of NO3 with NaCl and KBr: a nonphotolytic source of halogen atoms

Seisel, Sabine
•
Caloz, Francois
•
Fenter, Frederick F.
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1997
Geophysical Research Letters

The heterogeneous reactions of NO3 on NaCl and KBr salt were studied at room temp. using a Knudsen reactor equipped with dual detection, namely Laser induced fluorescence and mass spectrometry. The uptake coeffs. of NO3 were g=(4.9+-3).10-2 onto NaCl and g=0.16+-0.08 onto KBr. In the case of NaCl, HCl was the sole product obsd. However, there is indirect evidence that Cl atoms are the primary products. In the case of KBr we obsd. Br2 and Br to be the products of reaction. A first estn. of the atm. relevance of these reactions indicate that under certain conditions the heterogeneous loss of NO3 on sea-salt aerosols may compete with removal by homogeneous gas phase reactions.

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Type
research article
DOI
10.1029/97GL02857
Author(s)
Seisel, Sabine
Caloz, Francois
Fenter, Frederick F.
van den Bergh, Hubert  
Rossi, Michel J.  
Date Issued

1997

Published in
Geophysical Research Letters
Volume

24

Issue

22

Start page

2757

End page

2760

Subjects

7726-95-6 (Bromine)

•

7782-50-5 (Chlorine) Role: GFM (Geological or astronomical formation)

•

GPR (Geological or astronomical process)

•

FORM (Formation

•

nonpreparative)

•

PROC (Process) (heterogeneous reaction of NO3 with NaCl and KBr

•

a nonphotolytic sour

•

atm nitrogen oxide nonphotolytic chlorine bromine

Note

Copyright 2003 ACS

CAPLUS

AN 1997:777650

CAN 128:64200

53-10

Mineralogical and Geological Chemistry

Laboratoire de Pollution Atmospherique et Sol (LPAS),Swiss Federal Institute of Technology (EPFL),Lausanne,Switz. FIELD URL:

Journal

GPRLAJ

written in English.

Atmosphere; Troposphere (heterogeneous reaction of NO3 with NaCl and KBr, a nonphotolytic source of halogen atoms)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPAS  
Available on Infoscience
February 1, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/63736
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