Multiple oscillations observed in the rotational state population of molecular iodine(B) formed in the photodissociation of the molecular iodine dimer((I2)2)

• Published in: Journal of Chemical Physics, num. 92
• Publication date: 1990

Several oscillations are obsd. in the rotational state population of I2 B3P(Ou+) produced in the photodissocn. (I2)2 + hn -> I2(Bu',J') + I2(X). The initial excitation is above the dissocn. limit of the I2 B state. These oscillations are pronounced on some u' states, but not on others. For a given state u', the rotational state population oscillations essentially do not depend on the photolysis wavelength over the range of applied conditions.

Keywords: 7553-56-2P (Molecular iodine) Role: FORM (Formation ; nonpreparative) ; PREP (Preparation) (formation of ; in photodissocn. of mol. iodine dimer ; multiple oscillations in rotational state population of); 25730-91-0 Role: RCT (Reactant) ; RACT (Reactant or r ; iodine photodissocn rotational population photoproduct

Note:

Copyright 2003 ACS

CAPLUS

AN 1990:108348

CAN 112:108348

74-1

Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes

Lab. Chim. Tech.,Ec. Polytech. Fed. Lausanne,Lausanne,Switz. FIELD URL:

Journal

JCPSA6

written in English.

Photolysis (laser-induced, of mol. iodine dimer, multiple oscillations in rotational state population of mol. iodine produced in); Energy level (rotational, of mol. iodine photoproduced from mol. iodine dimer, oscillations in state population of)

Reference

• EPFL-ARTICLE-162833
• doi:10.1063/1.458476

Record created on 2011-02-01, modified on 2016-08-09