Multiple oscillations observed in the rotational state population of molecular iodine(B) formed in the photodissociation of the molecular iodine dimer((I2)2)
Several oscillations are obsd. in the rotational state population of I2 B3P(Ou+) produced in the photodissocn. (I2)2 + hn -> I2(Bu',J') + I2(X). The initial excitation is above the dissocn. limit of the I2 B state. These oscillations are pronounced on some u' states, but not on others. For a given state u', the rotational state population oscillations essentially do not depend on the photolysis wavelength over the range of applied conditions.
Keywords: 7553-56-2P (Molecular iodine) Role: FORM (Formation ; nonpreparative) ; PREP (Preparation) (formation of ; in photodissocn. of mol. iodine dimer ; multiple oscillations in rotational state population of); 25730-91-0 Role: RCT (Reactant) ; RACT (Reactant or r ; iodine photodissocn rotational population photoproduct
Copyright 2003 ACS
Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes
Lab. Chim. Tech.,Ec. Polytech. Fed. Lausanne,Lausanne,Switz. FIELD URL:
written in English.
Photolysis (laser-induced, of mol. iodine dimer, multiple oscillations in rotational state population of mol. iodine produced in); Energy level (rotational, of mol. iodine photoproduced from mol. iodine dimer, oscillations in state population of)
Record created on 2011-02-01, modified on 2016-08-09