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  4. Multiple oscillations observed in the rotational state population of molecular iodine(B) formed in the photodissociation of the molecular iodine dimer((I2)2)
 
research article

Multiple oscillations observed in the rotational state population of molecular iodine(B) formed in the photodissociation of the molecular iodine dimer((I2)2)

Philippoz, J. M.
•
Monot, R.
•
Van den Bergh, H.  
1990
The Journal of Chemical Physics

Several oscillations are obsd. in the rotational state population of I2 B3P(Ou+) produced in the photodissocn. (I2)2 + hn -> I2(Bu',J') + I2(X). The initial excitation is above the dissocn. limit of the I2 B state. These oscillations are pronounced on some u' states, but not on others. For a given state u', the rotational state population oscillations essentially do not depend on the photolysis wavelength over the range of applied conditions.

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Type
research article
DOI
10.1063/1.458476
Author(s)
Philippoz, J. M.
Monot, R.
Van den Bergh, H.  
Date Issued

1990

Published in
The Journal of Chemical Physics
Volume

92

Issue

1

Start page

288

End page

291

Subjects

7553-56-2P (Molecular iodine) Role: FORM (Formation

•

nonpreparative)

•

PREP (Preparation) (formation of

•

in photodissocn. of mol. iodine dimer

•

multiple oscillations in rotational state population of); 25730-91-0 Role: RCT (Reactant)

•

RACT (Reactant or r

•

iodine photodissocn rotational population photoproduct

Note

Copyright 2003 ACS

CAPLUS

AN 1990:108348

CAN 112:108348

74-1

Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes

Lab. Chim. Tech.,Ec. Polytech. Fed. Lausanne,Lausanne,Switz. FIELD URL:

Journal

JCPSA6

written in English.

Photolysis (laser-induced, of mol. iodine dimer, multiple oscillations in rotational state population of mol. iodine produced in); Energy level (rotational, of mol. iodine photoproduced from mol. iodine dimer, oscillations in state population of)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPAS  
Available on Infoscience
February 1, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/63679
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