Time-resolved measurement of difluoromethylene radical formation in the infrared multiphoton dissociation of chlorodifluoromethane
1979
Abstract
The IR multiphonon dissocn. of CF2HCl was investigated by monitoring the appearance of the CF2 product in real time during and after the laser pulse. The difluorcarbene radicals were detected quant. by their optical absorption in the ~A1B1->~X1A1 band system around 250 nm. The fragmentation was studied under collision-free conditions as well as in the presence of up to 500 torr Ar.
Details
Title
Time-resolved measurement of difluoromethylene radical formation in the infrared multiphoton dissociation of chlorodifluoromethane
Author(s)
Duperrex, R. ; Van den Bergh, H.
Published in
Journal of Chemical Physics
Volume
71
Issue
9
Pages
3613
Date
1979
Keywords
2154-59-8P Role: FORM (Formation; nonpreparative); PREP (Preparation) (formation of; in multiphoton IR laser-induced photolysis of chlorodifluoromethane; time-resolved measurement of); 7440-37-1 Role: RCT (Reactant); RACT (Reactant or reagent) (multipho; IR multiphoton photolysis chlorodifluoromethane; fluoromethylene radical photolysis chlorodifluormethane; methane chlorodifluoro IR multiphoton photolysis
Note
Copyright 2003 ACS
CAPLUS
AN 1980:119620
CAN 92:119620
74-1
Radiation Chemistry, Photochemistry, and Photographic Processes
73
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
JCPSA6
written in English.
Photolysis (IR, laser-induced, multiphoton, of chlorodifluoromethane, difluoromethylene radical formation in, time-resolved measurement of)
CAPLUS
AN 1980:119620
CAN 92:119620
74-1
Radiation Chemistry, Photochemistry, and Photographic Processes
73
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
JCPSA6
written in English.
Photolysis (IR, laser-induced, multiphoton, of chlorodifluoromethane, difluoromethylene radical formation in, time-resolved measurement of)
Laboratories
LPAS
Record Appears in
Scientific production and competences > ENAC - School of Architecture, Civil and Environmental Engineering > ENAC Archives > LPAS - Air and Soil Pollution Laboratory
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2011-02-01