Nitrogen oxide-catalyzed recombination of iodine atoms. Elementary steps of the complex mechanism

The recombination of I atoms in the presence of NO was studied by laser flash photolysis in the inert gas He, at pressures between 1 and 200 atm and at temps. from 320-440 DegK. The elementary steps of the complex mechanism of the recombination were resolved. The fall-off curve of the interaction I + NO + He -> INO + He was measured as well as the equil. const. for I + NO .tautm. INO. The bond energy of INO is DH00 = 23 +- 3 kcal mole-1.


Published in:
Chemical Physics Letters, 31, 2, 351-354
Year:
1975
Keywords:
Note:
Copyright 2003 ACS
CAPLUS
AN 1975:175753
CAN 82:175753
67-2
Catalysis and Reaction Kinetics
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
CHPLBC
written in English.
Recombination catalysts (nitric oxide, for iodine atoms); Recombination (of iodine atoms, mechanism of nitric oxide-catalyzed); Kinetics of recombination (of iodine atoms, with nitric oxide catalysis)
Laboratories:




 Record created 2011-02-01, last modified 2018-09-13


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