Nitrogen oxide-catalyzed recombination of iodine atoms. Elementary steps of the complex mechanism
The recombination of I atoms in the presence of NO was studied by laser flash photolysis in the inert gas He, at pressures between 1 and 200 atm and at temps. from 320-440 DegK. The elementary steps of the complex mechanism of the recombination were resolved. The fall-off curve of the interaction I + NO + He -> INO + He was measured as well as the equil. const. for I + NO .tautm. INO. The bond energy of INO is DH00 = 23 +- 3 kcal mole-1.
Keywords: 10102-43-9 Role: CAT (Catalyst use) ; USES (Uses) (catalysis by ; of iodine atom recombination) ; 14362-44-8 Role: RCT (Reactant) ; RACT (Reactant or reagent) (recombination of ; nitric oxide catalysis of) ; nitric oxide catalysis iodine recombination
Copyright 2003 ACS
Catalysis and Reaction Kinetics
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
written in English.
Recombination catalysts (nitric oxide, for iodine atoms); Recombination (of iodine atoms, mechanism of nitric oxide-catalyzed); Kinetics of recombination (of iodine atoms, with nitric oxide catalysis)
Record created on 2011-02-01, modified on 2016-08-09