Spectroscopic measurement of the rate of the gas-phase combination of methyl radicals with nitric oxide and oxygen at 295.deg.K
1971
Abstract
The rates of combination of Me. with NO and O2 were measured by flash spectroscopy at 295 DegK. The highpressure rate coeff. for Me. + NO(+M) -> MeNO(+M) was recorded as 1.0(+-0.15) * 1013 cm3 mole-1 sec-1. The low-pressure fall-off was interpreted with the Rice-Marcus model for D0(Me-NO) = 46.8kcal mole-1. The high-pressure rate coeff. for Me + O2(+M) -> MeO2(+M) was deduced to be .apprx.1.1 * 1012 cm3 mole-1 sec-1.
Details
Title
Spectroscopic measurement of the rate of the gas-phase combination of methyl radicals with nitric oxide and oxygen at 295.deg.K
Author(s)
Van den Bergh, H. E. ; Callear, A. B.
Published in
Transactions of the Faraday Society
Volume
67
Issue
7
Pages
2017-2024
Date
1971
Keywords
2229-07-4 Role: RCT (Reactant); RACT (Reactant or reagent) (reaction of; with nitrogen oxide and oxygen); 7782-44-7; 10102-43-9 Role: RCT (Reactant); RACT (Reactant or reagent) (with methyl radicals; kinetics of); methyl radical combination kinetics; nitric oxide combination kinetics; oxygen combination kinetics
Note
CAPLUS
AN 1971:467935
CAN 75:67935
67
Catalysis and Reaction Kinetics
Phys. Chem. Lab.,Cambridge,UK. FIELD URL:
TFSOA4
Bonds (energy of, carbon-nitrogen in nitroso methane); Kinetics (of methyl radicals, with nitrogen oxide and oxygen)
AN 1971:467935
CAN 75:67935
67
Catalysis and Reaction Kinetics
Phys. Chem. Lab.,Cambridge,UK. FIELD URL:
TFSOA4
Bonds (energy of, carbon-nitrogen in nitroso methane); Kinetics (of methyl radicals, with nitrogen oxide and oxygen)
Laboratories
LPAS
Record Appears in
Scientific production and competences > ENAC - School of Architecture, Civil and Environmental Engineering > ENAC Archives > LPAS - Air and Soil Pollution Laboratory
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2011-02-01