Experimental determination of the oscillator strength of the 2160 A band of the free methyl radical and a spectroscopic measurement of the combination rate

The f-value of the 2160-.ANG. band of the free Me radical was detd. exptl. as (1.2 +- 0.2) * 10-2. The rate coeff. for combination is (2.43 +- 0.24) * 1013 cm3/mole-sec at 293 DegK. Me radicals were generated by the flash photolysis of small partial pressures of both Me2Hg and azomethane with Ar added to 100 torr in all expts.


Published in:
Chemical Physics Letters, 4, 2, 101-102
Year:
1969
Keywords:
Note:
Copyright 2003 ACS
CAPLUS
AN 1970:16980
CAN 72:16980
73
Spectra by Absorption, Emission, Reflection, or Magnetic Resonance, and Other Optical Properties
Phys. Chem. Lab.,Cambridge,UK. FIELD URL:
Journal
CHPLBC
written in English.
Spectra (of methyl radical, oscillator strength of bands in)
Laboratories:




 Record created 2011-02-01, last modified 2018-01-28


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)