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research article

Product formation in rhodopsin by fast hydrogen motions

Weingart, Oliver
•
Altoè, Piero
•
Stenta, Marco
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2011
Physical Chemistry Chemical Physics

The photochemical cis-trans isomerization of retinal in rhodopsin is investigated by structure sampling and excited state QM/MM trajectories with surface hopping. The calculations uncover the motions responsible for photoproduct formation and elucidate the reasons behind the efficient photoisomerization in the primary event of visual transduction.

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c0cp02496a.pdf

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Publisher's Version

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http://purl.org/coar/version/c_970fb48d4fbd8a85

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openaccess

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1.8 MB

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Adobe PDF

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996b6fb5c4bdfdc87dd17b6695f407e8

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