Influence of water-soluble sulfonated phosphine ligands on ruthenium catalyzed generation of hydrogen from formic acid

Hydrogen can be generated from formic acid in aq. phase homogeneous catalytic reactions using ruthenium catalysts with water-sol. phosphine ligands. A comparison of tri-, di-, and mono-sulfonato triphenylphosphine, disulfonato diphenyl-alkyl-phosphines (Ph2PR; R=Me, n-Bu, Cyp), and monosulfonato phenyl-dialkyl-phosphines (PhPR2; R=Me, Cyp) is described. Using two equiv. of water-sol. phosphine per ruthenium ion, significant turnover frequencies are obsd. for the decompn. of formic acid. The influence of basicity, water soly. (related to the structures and behavior in aq. soln.), electronic properties, and steric effects of the phosphines on the rate of the hydrogen generation are investigated.


Published in:
Journal of Coordination Chemistry , 63, 14-16, 2685-2694
Year:
2010
Publisher:
Taylor & Francis
ISSN:
0095-8972
Keywords:
Laboratories:




 Record created 2010-12-14, last modified 2018-03-17


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