Synthesis of (E,Z)-1-Alkoxy-3-acyloxy-2-methylpenta-1,3-dienes via Danishefsky-Type Dienes or O-Acylation of Enones

• Published in: Journal Of Organic Chemistry, vol. 74, p. 8882-8885
• Publication date: 2009

1-Alkoxy-2-methyl-3-acyloxy-(E,E)-penta-1,3-dienes have been prepared applying among others a modified Danishefsky's general method, including chiral, racemic, and achiral derivatives.

Keywords: Diels-Alder Reactions ; Acid-Catalyzed Cyclocondensation ; Chiral Organoaluminum Reagent ; Prepared Cab Catalysts ; Activated Dienes ; Sulfur-Dioxide ; Asymmetric-Synthesis ; Enantioselective Synthesis ; Stereoselective-Synthesis ; Organic-Chemistry

Reference

• EPFL-ARTICLE-159203
• doi:10.1021/jo901878b
• View record in Web of Science

Record created on 2010-11-30, modified on 2017-05-12