The enantioselective Morita-Baylis-Hillman reaction and its aza counterpart

This review summarizes recent mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions. [on SciFinder (R)]


Published in:
Angewandte Chemie, International Edition, 46, 25, 4614-4628
Year:
2007
Keywords:
Baylis-Hillman reaction (Morita-; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Lewis acids Role: CAT (Catalyst use) ; USES (Uses) (chiral ; organo-; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Lewis bases Role: CAT (Catalyst use) ; USES (Uses) (organo ; chiral; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Bronsted acids Role: CAT (Catalyst use) ; USES (Uses) (organo- ; chiral; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Ionic liquids (organo-; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Reaction mechanism; Stereoselective synthesis (review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Amino acids; Phosphines Role: CAT (Catalyst use) ; USES (Uses) (review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Addition reaction; Addition reaction catalysts (stereoselective ; MBH- ; aza-MBH-; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Amines Role: CAT (Catalyst use) ; USES (Uses) (tertiary ; organo ; chiral; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions) ; review Morita Baylis Hillman aza mechanism enantioselective organo catalyst
Note:
CAN 147:300749
23-0
Aliphatic Compounds
Institut de CHimie des Substances Naturelles,CNRS,Gif-sur-Yvette,Fr.
Journal; General Review
1433-7851
written in English.
Laboratories:




 Record created 2010-11-25, last modified 2018-03-17


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