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research article

Effective Forces in Square Well and Square Shoulder Fluids

Fiocco, Davide  
•
Pastore, Giorgio
•
Foffi, Giuseppe  
2010
The Journal of Physical Chemistry B

We derive an analytical expression for the effective force between a pair of macrospheres immersed in a sea of microspheres, in the case where the interaction between the two unlike species is assumed to be a square well or a square shoulder of given range and depth (or height). This formula extends a similar one developed in the case of hard core interactions only. Qualitative features of such effective force and the resulting phase diagrams are then analyzed in the limit of no interaction between the small particles. Approximate force profiles are then obtained by means of integral equation theories (PY and HNC) combined with the superposition approximation and compared with exact ones from direct Monte Carlo simulations.

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Type
research article
DOI
10.1021/jp105145x
Author(s)
Fiocco, Davide  
Pastore, Giorgio
Foffi, Giuseppe  
Date Issued

2010

Publisher

American Chemical Society

Published in
The Journal of Physical Chemistry B
Volume

114

Issue

37

Article Number

12085

Subjects

Phase-Transitions

•

Colloids

•

Suspensions

•

Simulation

•

Mixtures

•

Behavior

•

Equation

•

System

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GR-FO  
Available on Infoscience
September 6, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/52805
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