Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH+, as an active intermediate species, producing hydrogen peroxide and hydrogen in aerobic and anaerobic conditions, respectively.


Published in:
Chemical Communications- Royal Society of Chemistry, 46, 17, 2918-2919
Year:
2010
Publisher:
Royal Society of Chemistry
ISSN:
1359-7345
Keywords:
Laboratories:




 Record created 2010-03-25, last modified 2018-03-18

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