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research article
Structure of 1,4,10,19,25,41-C70(CF3)6, isomer with unique arrangement of addends
A novel isomer of C70(CF3)6 has been isolated by HPLC from a mixture prepared by trifluoromethylation of C70 with CF3COOAg. The X-ray structure revealed an unprecedented arrangement of CF3 groups forming a p3mp ribbon. This result provides additional evidence of the preferable formation of trifluoromethylated fullerene molecules comprising a single continuous ribbon of edge-sharing para- and meta-C6(CF3)2 hexagons.
Type
research article
Web of Science ID
WOS:000242520800011
Authors
Dorozhkin, E.I.
•
Ignat’eva, D.V.
•
Tamm, N.B.
•
Vasilyuk, N.V.
•
Goryunkov, A.A.
•
Avdoshenko, S.M.
•
Ioffe, I.N.
•
Sidorov, L.N.
•
•
Kemnitz, E
Publication date
2006
Published in
Volume
127
Issue
10
Start page
1344
End page
1348
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
January 13, 2010
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