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research article

Direct Alkynylation of Indole and Pyrrole Heterocycles

Brand, Jonathan P.  
•
Charpentier, Julie
•
Waser, Jerome  
2009
Angewandte Chemie International Edition

Easy does it: The unique properties of benziodoxolone alkynyl periodinane 1 and gold catalysts have allowed the development of a high yielding, operationally simple (room temperature, no dry solvents or inert conditions, commercially available catalyst) reaction for the introduction of silylacetylenes on a large range of indole and pyrrole heterocycles with a wide range of functional groups (see scheme).

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ACIE2009-9346GreenAccess.pdf

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