Continuous high-temperature polymerization of MMA at pilot scale
2005
Abstract
The kinetic properties of the Me methacrylate (MMA) polymn. at pilot scale for a given temp. range (130-170 Deg) were detd. by differential scanning calorimetry and batch expts. reflecting initiation by MMA peroxides, depropagation of the living chains as well as high temp. gel effect. All different aspects were included in a general model for the description of the continuous process, allowing the prediction of conversion evolution and mol. wt. distributions. The calcd. data were compared with that from the pilot process and verified.
Details
Title
Continuous high-temperature polymerization of MMA at pilot scale
Author(s)
Nising, Philip ; Meyer, Thierry
Published in
AIChE Annual Meeting, Conference Proceedings, Cincinnati, OH, United States, Oct. 30-Nov. 4, 2005
Pages
555g/1-555g/5
Date
2005
Keywords
Note
CAN 146:122352
35-3
Chemistry of Synthetic High Polymers
Polymer Reaction Engineering, ISIC-GPM,EPFL (Swiss Federal Institute of Technology),Lausanne,Switz.
Conference; Computer Optical Disk
written in English.
80-62-6 (Methyl methacrylate) Role: PRP (Properties), RCT (Reactant), RACT (Reactant or reagent) (kinetics of continuous high-temp. polymn. of MMA at pilot scale); 9011-14-7P (PMMA) Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (kinetics of continuous high-temp. polymn. of MMA at pilot scale)
35-3
Chemistry of Synthetic High Polymers
Polymer Reaction Engineering, ISIC-GPM,EPFL (Swiss Federal Institute of Technology),Lausanne,Switz.
Conference; Computer Optical Disk
written in English.
80-62-6 (Methyl methacrylate) Role: PRP (Properties), RCT (Reactant), RACT (Reactant or reagent) (kinetics of continuous high-temp. polymn. of MMA at pilot scale); 9011-14-7P (PMMA) Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (kinetics of continuous high-temp. polymn. of MMA at pilot scale)
Laboratories
GSCP
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > GSCP - Group of Chemical and Physical Safety
Peer-reviewed publications
Conference Papers
Work produced at EPFL
Published
Peer-reviewed publications
Conference Papers
Work produced at EPFL
Published
Record creation date
2009-02-09