Highly filled Polystyrene-laponite nanocomposites prepared by emulsion polymerization
2009
Abstract
Polystyrene-based nanocomposite films containing up to 20 wt% laponite clay have been prepared by emulsion polymerization. Significant increases in the storage and tensile moduli were observed in both the glassy and rubbery state on laponite addition. However, whereas in the glassy state these increases were correlated with the extent of exfoliation of the laponite, in the rubbery state they were more dependent on the overall laponite content. These results are discussed in terms of the observed morphologies and micromechanical models for the reinforcing effect of rigid nano-sized filler particles.
Details
Title
Highly filled Polystyrene-laponite nanocomposites prepared by emulsion polymerization
Author(s)
Ruggerone, R. ; Plummer, C. J. G. ; Herrera, N. N. ; Bourgeat-Lamib, E. ; Manson, J. A. E.
Published in
European Polymer Journal
Volume
45
Issue
3
Pages
621-629
Date
2009
ISSN
0014-3057
Keywords
polystyrene; laponite; nanocomposites; mechanical properties; Emulsion; emulsion polymerization; MECHANICAL-PROPERTIES; CLAY NANOCOMPOSITES; POLYMER/CLAY; NANOCOMPOSITES; POLYSTYRENE/MONTMORILLONITE NANOCOMPOSITE; MONTMORILLONITE NANOCOMPOSITES; PARTICLE-SIZE; COMPOSITES; BEHAVIOR; POLYURETHANE; MORPHOLOGY
Note
[Ruggerone, Riccardo Plummer, Christopher J. G. Manson, Jan-Anders E.] Ecole Polytech Fed Lausanne, LTC, Stn 12, CH-1015 Lausanne, Switzerland. [Herrera, Norma Negrete Bourgeat-Lami, Elodie] CNRS CPE UCBL, UMR 5265, LCPP C2P2, F-69616 Villeurbanne, France. Manson, JAE, Ecole Polytech Fed Lausanne, LTC, Stn 12, CH-1015 Lausanne, Switzerland. jan-anders.manson@epfl.ch
ISI Document Delivery No.: 419PY
Cited Reference Count: 55
Ruggerone, Riccardo Plummer, Christopher J. G. Herrera, Norma Negrete Bourgeat-Lami, Elodie Manson, Jan-Anders E.
European Framework 6 Project NAPOLEON ; Centre Interdisciplinaire de Microscopie Electronique (CIME) of the EPFL
This work was supported by the European Framework 6 Project NAPOLEON and technical support was provided the Centre Interdisciplinaire de Microscopie Electronique (CIME) of the EPFL.
PERGAMON-ELSEVIER SCIENCE LTD
OXFORD
ISI Document Delivery No.: 419PY
Cited Reference Count: 55
Ruggerone, Riccardo Plummer, Christopher J. G. Herrera, Norma Negrete Bourgeat-Lami, Elodie Manson, Jan-Anders E.
European Framework 6 Project NAPOLEON ; Centre Interdisciplinaire de Microscopie Electronique (CIME) of the EPFL
This work was supported by the European Framework 6 Project NAPOLEON and technical support was provided the Centre Interdisciplinaire de Microscopie Electronique (CIME) of the EPFL.
PERGAMON-ELSEVIER SCIENCE LTD
OXFORD
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Laboratories
LTC
Record Appears in
Scientific production and competences > STI - School of Engineering > STI Archives > LTC - Laboratory of Composite and Polymer Technology
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2009-01-13