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  4. Palladium nanoparticles stabilized by an ionic polymer and ionic liquid: A versatile system for C-C cross-coupling reactions
 
research article

Palladium nanoparticles stabilized by an ionic polymer and ionic liquid: A versatile system for C-C cross-coupling reactions

Yang, Xue
•
Fei, Zhaofu  
•
Zhao, Dongbin  
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2008
Inorganic Chemistry

Highly stable palladium nanoparticles 5 nm diam., protected by an imidazolium-based ionic polymer in a nitrile-functionalized ionic liq., have been prepd. and characterized by TEM. These Pd nanoparticles are excellent precatalysts for Suzuki, Heck, and Stille coupling reactions and can be stored without undergoing degrdn. for at ³2 yr. The nanoparticle system may therefore be considered as an alternative to the traditional palladium on carbon precatalyst used in many C-C coupling reactions, and also allowing reactions to be conducted under solvent-free conditions.

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Type
research article
DOI
10.1021/ic702305t
Web of Science ID

WOS:000254902000053

Author(s)
Yang, Xue
Fei, Zhaofu  
Zhao, Dongbin  
Ang, Wee Han  
Li, Yongdan  
Dyson, Paul J.  
Date Issued

2008

Published in
Inorganic Chemistry
Volume

47

Issue

8

Start page

3292

End page

3297

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCOM  
Available on Infoscience
July 29, 2008
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/27146
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