Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes
In the presence of moderately strong acids in MeCN, Co complexes with BF2-bridged diglyoxime ligands are active catalysts for the redn. of protons to H2 at potentials as pos. as -0.28 V vs. SCE. [on SciFinder (R)]
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Hu, X., Cossairt, B. M., Brunschwig, B. S., Lewis, N. S., & Peters, J. C. (2005). Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chemical Communications (ChemComm), (37), 4723–4725. https://doi.org/10.1039/b509188h
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2005
37
4723
4725
CAN 144:12834 72-2 Electrochemistry Division of Chemistry and Chemical Engineering, Arnold and Mabel Beckman Laboratories of Chemical Synthesis,California Institute of Technology,Pasadena,CA,USA. Journal 1359-7345 written in English. 104422-08-4; 130247-28-8 Role: CAT (Catalyst use), RCT (Reactant), USES (Uses), RACT (Reactant or reagent) (electrocatalyst for hydrogen evolution in acetonitrile contg. strong acids); 1333-74-0 (Hydrogen) Role: FMU (Formation, unclassified), FORM (Formation, nonpreparative) (electrochem. evolution in acetonitrile contg. strong acids in presence of cobalt difluoroboryl diglyoximato complex catalysts); 870074-49-0; 870074-50-3 Role: FMU (Formation, unclassified), PRP (Properties), FORM (Formation, nonpreparative) (electrochem. reductive formation in acetonitrile); 870074-51-4 Role: FMU (Formation, unclassified), FORM (Formation, nonpreparative) (formation in hydrogen electrocatalytic evolution at cobalt difluoroboryl diglyoximato complex in acetonitrile contg. HCl); 870074-52-5 Role: FMU (Formation, unclassified), FORM (Formation, nonpreparative) (formation in hydrogen electrocatalytic evolution in presence of CO at cobalt difluoroboryl diglyoximato complex in acetonitrile); 76-05-1 (Trifluoroacetic acid) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PROC (Process) (hydrogen electrocatalytic evolution at cobalt difluoroboryl diglyoximato complex in acetonitrile contg.); 7647-01-0 (Hydrochloric acid); 67969-82-8 Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PROC (Process) (hydrogen electrocatalytic evolution at cobalt difluoroboryl diglyoximato complexes e in acetonitrile contg.); 630-08-0 (Carbon monoxide) Role: RCT (Reactant), RACT (Reactant or reagent) (hydrogen electrocatalytic evolution in presence of CO at cobalt difluoroboryl diglyoximato complex in acetonitrile); 870074-53-6P Role: PNU (Preparation, unclassified), RCT (Reactant), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction with HCl)
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