Identification of iron cyclam complexes encapsulated inside zeolite Y

The combination of EPR and Mossbauer spectroscopy along with IR, Diffuse Reflectance UV-visible, and XRD techniques proved to be a powerful tool for identifying and characterizing the mol. and electronic structure of various Fe complexes formed inside the supercages of zeolite-Y. Esp. interesting is the identification of encapsulated trans-[(cyclam)Fe(N3)2]+@NaY, as a potent precursor for the synthesis of catalytically active Fe(V) nitrido species. [on SciFinder (R)]


Published in:
Inorganica Chimica Acta, 337, 53-58
Year:
2002
Keywords:
Note:
CAN 138:80084 73-4 Optical, Electron, and Mass Spectroscopy and Other Related Properties Department of Chemistry and Biochemistry,University of California, San Diego,La Jolla,CA,USA. Journal 0020-1693 written in English. 7439-89-6 (Iron); 20074-52-6 (Iron 3+) Role: PRP (Properties) (identification of iron cyclam complexes encapsulated inside zeolite Y); 481646-04-2P; 481667-80-5P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (identification of iron cyclam complexes encapsulated inside zeolite Y); 295-37-4 (Cyclam); 4648-54-8 (Trimethylsilyl azide); 7705-08-0 (Iron trichloride) Role: RCT (Reactant), RACT (Reactant or reagent) (iron cyclam complexes encapsulated inside zeolite Y using)
Laboratories:




 Record created 2007-12-17, last modified 2018-03-17


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