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  4. Cavity ring-down spectroscopy of jet-cooled silane isotopologues in the Si-H stretch overtone region
 
research article

Cavity ring-down spectroscopy of jet-cooled silane isotopologues in the Si-H stretch overtone region

Bisson, Régis  
•
Dang, Tung T.  
•
Sacchi, Marco  
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2007
The Journal of Chemical Physics

Absorption spectra of silane in the region of the first overtone of the Si-H stretch vibration have been recorded in a seeded supersonic jet expansion by cavity ring-down spectroscopy as well as in a static gas cell at room temperature by photoacoustic spectroscopy. Spectral simplification due to strong rotational cooling in the jet expansion enables us to clearly resolve and assign the rovibrational transitions of the (2000) and (1100) bands of the three isotopologues 28SiH4, 29SiH4 and 30SiH4 in their natural isotopic abundance. Interconversion between different nuclear spin species of SiH4 is found to be absent during the jet expansion. Isotope shifts for 29SiH4 and 30SiH4 relative to 28SiH4 are measured and found to be suitable for selective vibrational excitation of any of three silane isotopologues by pulsed laser excitation in a jet expansion.

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Type
research article
DOI
10.1063/1.2819072
Web of Science ID

WOS:000251987800007

Author(s)
Bisson, Régis  
Dang, Tung T.  
Sacchi, Marco  
Beck, Rainer D.  
Date Issued

2007

Published in
The Journal of Chemical Physics
Volume

127

Issue

24

Article Number

244301

Subjects

Silane isotopologue

•

Silicon isotope

•

Cavity ring-down spectroscopy

•

Supersonic jet expansion

•

Isotope shift

•

first Si-H stretch overtone

Note

Selected for January 14, 2008 issue of Virtual Journal of Nanoscale Science & Technology

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCPM  
Available on Infoscience
November 8, 2007
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/14486
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