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research article
Total Synthesis, Configuration, and Biological Evaluation of Anguinomycin C
Immunofluorescence assays indicate that anguinomycin C is a potent inhibitor of protein export from the nucleus. Key features in the total synthesis of this antitumor natural product include a Cr-catalyzed enantioselective hetero-Diels– Alder reaction, a Negishi reaction with stereoinversion, and application of the DIOZ auxiliary.
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ACIE 2007, 46, 8707.pdf
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